Abstract:High fluorine groundwater is a typical poor quality water source. It can cause endemic high fluorine disease. In this study, taking YuchengPingyuan area as the research object, the fluorine content, hydrochemical types and influence factors have been studied. It is showed that most of the fluorine content in shallow groundwater is not more than 1.0mg/L, and hydrochemical types are mainly HCO3Na type and Cl·SO4Na type. Most of the fluorine content in deep groundwater is more than 1.0mg/L, and hydrochemical types are HCO3·SO4Na type and HCO3·ClNa type. Based on the study of pH and chemical evolution of groundwater, it is regarded that alkaline environment can promote fluorine ion aggregation to a certain extent. It is not the only decisive factor, and the formation mechanism of high fluorine water in this area are mainly waterrock interaction and evaporation concentration.