In the past 20 years, through four projects, such as ecogeochemical survey in the lower reaches of the Yellow River basin in Shandong Province, land quality geochemical survey and evaluation with the scale of the 1 : 250000 in Shandong province have been completed with financial funds. Based on geochemical survey data of 54 indexes, such as Ag, As, Au and B in surface soil, geochemical parameters and characteristics of surface soil in 17 cities of Shandong province have been studied by administrative region statistics. The geochemical background values of 17 cities of Shandong province have been determined. Comparing with those of the whole country and province, their differences have been analyzed.