Abstract:Since 2010, hydrogeological background and chemical testing data of water quality in different layers in studying area have been analyzed. Relation between the enrichment of trace element Fe3+and lithology in aqueous medium, pH value of groundwater, waterbearing property and oxidationreduction environment has been introduced emphatically. It is regarded that the most favorable environment for Fe3+enrichment is metamorphic rocks; HCO3Ca type water is widely distributed in carbonate and clastic rocks; the average content of Fe3+ is the lowest in carbonate type in groundwater; while the average content of Fe3+in sulfate type (including complex) groundwater in metamorphic rocks is the highest. Thus, it showes a positive correlation with Fe3+ . Fe3+ content in groundwater occurres a high concentration of zonation in auxiliary shaft and its surrounding areas.