Abstract:Through deduction of fourphase system digram of potassium formation, analyzing differences of Br element in the content of sylvite and carnallite variation, combining with research on carnallite crystal morphology, it is regarded that the appearance of potassium salt in the upper part, while carnallite potash (carnallite) in the lower part in Dongtai mine of Laos is caused by element migration and recrystallization role.