Abstract:EH 4 magnetolluric sounding system is an advanced prospecting instrument. Due to its advanges of light efficiency, exploration depth and reflect intuitively, it is widely used in mineral exploration and hydrological exploration. During karst fissure water prospecting in Zichuan area of Shandong province, through EH4 electromagnetic sounding work, combining with field hydrogeological investigation, under the condition of determining water supply and water bearing condition of the structural belt, waterbearing fault belts and fissure belts have been found. According to electric difference of geological ore bodies, width, depth, occurrence and water occurrence of structural belts have been determined. It is fit with the locations gained by drilling results. It indicates the direction of deep water exploration by using EH 4 electromagnetic system.