Abstract:Through environmental geology investigation and sample test, from the aspect of strata, weather, landform and hydrological aspects, comprehensive analysis has been carried out. It is regarded that distribution of high- fluorine groundwater and formation condition are controlled by geology, climate, landform and hydrogeology. In the process of infiltration, atmospheric precipitation will bring fluorine in the soil into the undergroundwater through water rock interaction and leaching, evaporated under the action of concentrated, and formed high fluorine groundwater.