Through comparing petrochemistry characteristics of Zouping volcanic basin, it is regarded that general trend of volcanic activity is from weak to strong, and explosive index is 386892. SI values of volcanic rocks in three sub-formation are less than 40, which indicate that mother magama originated from the mantle might experience a process of magmatic differentiation or magmatic assimilation. σ values of intrusive rocks are from 2.39 to 4.99,which belong to calcalkaline series. DI values are 65.15~88.98. It indicates that magmatic differentiation is high. A/NKC values are 65.15~88.98. It demonstrates inferior aluminous. Response of copper polymetallic deposit and tectonicmagmatic event can be described that inherited tectonic movement and multiple magma intrusion make alkaline magmatichydrothermal and crystallized monzonite occur metasomatism and alteration, and make oreforming material interchanges near their geochemical interface.