Tourmalinite in Liujia of west Shandong has black or dark-green colour pillar-shaped of fiber-like aggregate. According to electronic microprobe and X-ray diffraction analysis results, it is iron-magnesium tourmalinite which belongs to transitional type between dravite and iron tourmalinite. Its mineralization system is composed of two parts as: hydrothermal system and mineralization-controll environment. The genesis is similiar to quartz-vein.